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Gas Firms Dispute Methane Contamination Study [UPDATED]

Fracking

First Posted: 05/10/11 03:15 PM ET Updated: 07/10/11 06:12 AM ET

The natural gas industry on Tuesday was alternately disputing the findings of a new Duke University study on methane contamination of drinking water near gas well sites, or dismissing the study's results as highlighting an old problem that the industry and regulators are already fixing.

The study, published Monday in the Proceedings of the National Academy of Sciences, examined dozens of drinking water wells in northern Pennsylvania and southern New York. It found that concentrations of methane were, on average, 17 times higher in wells closer to active gas drilling sites than in wells where no gas development activity was underway nearby.

"We conclude that greater stewardship, data, and -- possibly -- regulation are needed to ensure the sustainable future of shale-gas extraction and to improve public confidence in its use," the authors of the study wrote.

But Chris Tucker, a spokesman for Energy in Depth, a group representing independent oil and gas developers, argued on Tuesday that the data set used by the Duke researchers was far too small to draw any broad conclusions about methane contamination.

"The biggest weakness is the lack of baseline data," Tucker argued. "It’s well known that methane migrates upward from source rock over the course of geologic time -- but these guys are trying to argue that it’s migrating upward almost instantaneously as a result of development. That’s just not a case you can credibly make with this sort of data set, these sort of assumptions, and this sort of methodology."

The lack of baseline data -- essentially measurements taken from the same water source both before drilling operations arrived, and then again after -- was recognized by the researchers as a weakness in the analysis.

But Dr. Stephen Osborn, one of the authors of the Duke study, suggested that the correlation implied by the analysis was nonetheless strong, and that water samples gathered from wells furthest from gas development will provide the sort of baseline data needed for future studies.

"Our sampling in non-active extraction areas are effectively baseline and will be important as natural gas extraction operations migrate into these areas," Osborn said. "We hope to continue sampling in these non-active areas as drilling and fracking occur there."

To be sure, methane can be found naturally in groundwater -- often in high concentrations in some parts of Pennsylvania. But according to the Duke study, the molecular characteristics of the methane found in the various wells the researchers examined suggested that industry, rather than naturally occurring events, was behind the increased methane concentrations.

The researchers conceded, however, that more study would be needed before such an assertion could be considered conclusive.

Even so, Matt Pitzarella, a spokesman for Range Resources, a natural gas developer with operations in Pennsylvania, said that methane migration tied to poorly designed wells is a well-known problem -- and one that state regulators in Pennsylvania have been endeavoring to fix for some time.

"Naturally occurring methane has been a long standing and documented issue in this part of the state, where Range is not as active," Pitzarella said in an email message. "Either way we employ the same high standards for well casing in the southwest even though the risk is significantly lower. It’s our job and that of regulators to ensure that natural gas drilling is responsible and does not exacerbate this issue. While the study has grabbed headlines, it’s actually old news and an issue that was addressed by state regulators and supported by industry several years ago."

That sentiment was echoed on the blog of Pennsylvania's former top environmental regulator, John Hanger.

Hanger noted, for example, that the state's Department of Environmental Protection had proposed new gas drilling rules in 2009, and those rules became final last February.

"The new rules raise standards for the design, construction and operation of gas wells to reduce gas migration pollution," Hanger said. "Gas migration has been a problem in Pennsylvania for decades, well before the first Marcellus well was drilled in 2005. The new, strong rules and the attention to this problem make this the time to reduce it sharply."

For all this, the Duke study appeared to lend a measure of support to long-standing complaints among some residents in areas of dense gas development that their drinking water supplies became infused with methane only after gas prospectors moved into the neighborhood.

That phenomenon prompted an entire genre of online videos depicting homeowners setting faucet water ablaze. Such imagery was among the most memorable arising from last year's Oscar-nominated documentary, "Gasland".

The study did not, however, reveal contamination from chemicals used in hydraulic fracturing, or fracking, the contentious process used in virtually all new drilling done in the area. It involves the high-pressure injection of water, sand and chemicals deep underground to break up and prop-open rock formations in order to release and extract the gas.

Environmental groups and residents had long feared that the chemicals were -- or could be-- finding their way from the well bore and into drinking water well, but the Duke study found no evidence of this.

This story has been updated with comments from Duke researchers.

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The natural gas industry on Tuesday was alternately disputing the findings of a new Duke University study on methane contamination of drinking water near gas well sites, or dismissing the study's resu...
The natural gas industry on Tuesday was alternately disputing the findings of a new Duke University study on methane contamination of drinking water near gas well sites, or dismissing the study's resu...
 
 
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IWantTofu
Evolution. Now a political position.
11:44 AM on 05/13/2011
They need to check if someone can light their water on fire, if neighbors have the same problem. If its consistent through a neighborhood getting water from the same aquifer, you could claim that there is a decent chance that the gas could be coming from gas wells. If its only one guy and the neighbors are all right, then its more likely a problem with the water well going through a shallow coal seam, and not being constructed properly. No one in these "gas in water" articles ever seem to investiage the possibility of the gas getting into the person's water supply from poor well construction.
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Chris Salmon
Geologist and Computer Scientist
08:43 PM on 05/12/2011
I just came across the most astounding admission by Dr. Rob Jackson, one of the authors and the contact person for this paper. Check this out, I was floored:

http://www.timesleader.com/FwBp/news/energy/Duke-study-finds-tainted-water-near-natural-gas-wells.html

Speaking to the issue of whether the sample locations were random, "Jackson said the study was indeed not random, but that was because they needed homeowners permission to test their water."

That means the samples are rife with self-selection bias. The samples are coming from wells owned by people who want their water to be tested! And .. wouldn't that be people who think or know they have a problem with their water and want to have it tested?!?! WOW!

How reliable are the study findings at this point? That's not a rhetorical question, I'd really like to know. We know now that the sample doesn't reflect the overall population of water wells, but only reflects a subset - those owned by people who want them to be tested. So then the findings are only valid for that subset, isn't that correct? I'm no pro stats guy but that seems pretty clear to me, however if someone can shed light on this, that would be great.
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02:21 PM on 05/13/2011
These "anti-frack" smear job (by so called environmentalists no less) just gets worse and worse.

A small sample non-randomized sample set is to be used as the basis for a nationwide ban. Meanwhile, coal miners rip the tops off of mountains and pour mercury into the ocean, and the "environmental advocates" say little to nothing.

I haven't seen the left cannibalize itself like Nader ripped Gore to pieces.
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JBDenver
1% - Not just for milk anymore
04:23 PM on 05/12/2011
Based on the photo...just think of all the money you could save by using water for your grill instead of propane.
IWantTofu
Evolution. Now a political position.
11:44 AM on 05/13/2011
Great idea. Think how much you could also save in heating fuel.
12:33 PM on 05/12/2011
* * * Since the contamination is stronger near the wells it looks like the gas drilling companies are using porous pipes way to close to the surface. * * *

Howard Scott Pearlman

5-12-2011
12:24 PM on 05/12/2011
Finding methane in drinking water that now ignites after drilling gas wells would indicate that the gas drill pipes are leaking gas into the water that supplies the family drinking water.

The Gas Industry's relutance to list all the chemicals that they are using for fracting certainly implies that they are using highly toxic, and dangerous chemicals.
12:09 PM on 05/12/2011
In the movie gasland they found carcinogenic chemicals from fracking that shot up the drill well into retention ponds that contaminated surface retention ponds. This water leaked into the environment.
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Chris Salmon
Geologist and Computer Scientist
03:55 PM on 05/11/2011
Personally, I have some questions about this study. However I try to stay open minded and not speak as though I know something I really don't yet know. I've written Dr. Jackson and asked him for the original dataset, including sample location coordinates and chemistries just to study and play around with the data for fun. Reading the paper two questions quickly come to mind:

1) an active drilling area is such because they believe there are commercial quantities of deep thermogenic methane present, of the kind found in the samples taken near these areas. An area that is not an active drilling area is such because they don't believe there are reservoirs of such gas present, which was also the kind of gas not found in the samples taken from those areas. It may be, that it would be impossible to find such gas in the samples where it was not found, because it's not present in those areas at all to begin with, whether you tried to drill for it or not. And that is, in fact, why those are not active drilling areas to begin with. I think comparing maps of the sample sites to maps of gas reservoirs could help answer this question. If the samples without thermogenic methane were taken outside the boundaries of reservoirs of this gas, then you'd never find it in those samples no matter what. That's just the first question that comes up.
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Chris Salmon
Geologist and Computer Scientist
04:09 PM on 05/11/2011
2) My second question is about sample locations. The paper did not discuss their methodology for choosing sample locations. The sample location map in the paper makes it appear, without knowing more detail, that a high percentage of the samples were taken around Dimock, PA - an area with a known methane contamination problem due to poor well completion and cement jobs by Cabot. If the sample population is high in samples taken from an area known to have a methane contamination problem previous to the study, then basically the study may be only saying that areas with a known methane contamination problem, have this problem, while other areas don't. If that's so, then this is a conclusion that can't be generally applied to gas drilling outside areas with a previously known problem and doesn't help understand risks associated with it.

I think further analysis and mapping of this data and comparing it to maps of other data would help clarify understanding of this study. But I don't disagree with this statement in their conclusion, either: "Greater stewardship, knowledge, and—possibly—regulation are needed to ensure the sustainable future of shale-gas extraction."
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07:05 PM on 05/11/2011
Before careful Chris. Sensible and well-informed posts about shale gas will flag you as an evil oil monger ;)

Seriously, good points both.

What's being lost here is the fundamental question of whether or not fracking creates broad containimation of the ground water. (Perhaps by creating pathways between shale gas and groundwater). The paper seems to answer this question in the negative, which would support the industry.

But the media spin seems to turn this into a blow against the industry, even though it seems to vindicate their core assumptions.
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lonewolfwisconsin
StandingOnYourGround-TreadingOnYourSnakeFlag
07:23 AM on 05/12/2011
It is obvious you have a vested interest in support of Fracking, while every sane, sensible, and honest human can correlate that before fracking they had no water issues, and after fracking their water went bad and they can ignite gases coming out of their faucets. It is the evil Capitalists that follow your line of thinking, which is ruing America inside and out.
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Chris Salmon
Geologist and Computer Scientist
09:12 AM on 05/12/2011
Actually, lonewolf, you are incorrect, I have no vested interest in gas drilling in PA, NY or elsewhere, nor this type of "controversial" hydraulic fracturing. In fact, my income is derived from my own oil production alone, and so actually I would benefit if natural gas, a direct competitor to me, were NOT produced at all, because this would very likely cause oil prices to rise - directly increasing my income. However the truth is, I do not want oil prices to rise and in fact I wish they were lower than they are now, maybe about $20/bbl lower.

It's unfortunate that you feel the hateful way you do, but that is all coming from inside you and has nothing to do with me. I do not deserve to be attacked in such a manner, called evil, and told I'm ruining America merely for asking good questions. Asking good questions is the beginning of discovering the truth of the material world. Attacking and insulting people who ask questions is a mistake and a blatant effort to squelch dissent and control thought in an effort to ensure the public has only your point of view available to them. Your choice to do that is not my problem.

You aren't being honest because you can't say for sure your statement regarding fracking and water is true. The authors of this study have been careful to avoid any such statement. In fact the study largely absolves fracking as the problem here.
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Chris Salmon
Geologist and Computer Scientist
09:44 AM on 05/12/2011
Lonewolf, I ran out of space in my reply but I just wanted to add that your attack on me doesn't bother me, make me angry at you, or cause me to dislike you. Just because you've chosen to dislike whatever image you think is me that only exists in your mind, doesn't mean I have to dislike you. We aren't enemies, we're all Americans trying to do what we think is best for our Nation and hopefully we're all interested in getting as close as we can to the real truth of this issue. I live by the assumption we all want as close to whatever truth as the best measurement of valid, reproducible and verifiable evidence can get us, no matter what that is. I think you and I both want that. It may be naive for me to think everyone does but I'd rather start from that assumption and slowly accept that it's wrong about some individuals based on their actions than prejudge people because I think they're in some category or group. Like, for instance, "evil Capitalists" :-)
03:20 PM on 05/11/2011
This my 4th time to post a comment on this website. None of the others made the cut. Most of the stuff I read here is just cheap shots by anonymous idiots who have never had an original thought. Fact is fact, truth is truth, no matter how it makes you feel. The earth is a living breathing thing made up of every chemical known to man. It is still growing and moving and changing every day. There is more polution and toxic chemicals released from volcanic activity in one day tha humans have caused to be released since we started using fire. I hope this post is not too traumatic for most of your readers. By the way my name is Greg King for real!!!
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ZaneDavid
03:51 PM on 05/11/2011
Good post......most, if not all will not believe a word of it.
Sad - ain't it.

*fan* for trying.
Oginikwe
I think therefore I'm dangerous
02:02 PM on 05/11/2011
This is ridiculous!! They want baseline data--are you kidding me? Do they think people drill wells for methane to heat their homes from their faucets? Non-plausible deniability.
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ZaneDavid
03:55 PM on 05/11/2011
Base line data is needed as almost all wells [for water] that are 'drilled' to a depth of less than 200 feet in up-state New York contain methane....just a fact of life up here.
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Chris Salmon
Geologist and Computer Scientist
05:39 PM on 05/11/2011
From the paper: "Methane concentrations were detected generally in 51 of 60
drinking-water wells (85%) across the region, regardless of gas
industry operations, but concentrations were substantially higher
closer to natural-gas wells"

http://www.nicholas.duke.edu/cgc/pnas2011.pdf
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Chris Salmon
Geologist and Computer Scientist
05:48 PM on 05/11/2011
but of course, correlation is not causation and it's expected that they would drill for methane in areas with higher concentrations of methane. They may (I don't know) have even done geochemical exploration studies at the surface and chosen those areas to drill because they found higher concentrations of thermogenic methane in soil samples or from some kind of remote sensing in those areas.
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Malcolm Hensley
Last of the Reagan Republicans
01:45 PM on 05/11/2011
I've read so many post from Anti-Frackers and frankly they could not hold their own in a debate with the Man made Climate Change Deniers!

So devoid of facts - they are so repulsed by facts it's scary!

A couple of points the report out of Duke University that survived peer review says we need more testing and regulations of fracking. I agree.

Want to know why we need more testing? I know the Anti-Frackers don't facts just irritate them.
But for the rest of the reasoned posters check out this web site.

http://www.elibrary.dep.state.pa.us/dsweb/Get/Version-48262/550-0800-001.pdf

Just in PA there were over 180,000 (this is not a misprint) oil wells drilled in PA before someone had the bright idea that they ought to be keeping records of where the wells were drilled!

Think about this; long before fracking in these same areas they lost the locations of over 180,000 wells!!! You think the small oil companies responsible for drilling these wells a 100 years ago plugged these wells!

As for methane coming out of your water tap, I saw this as a kid at my aunts house in PA in the
60's!
02:08 PM on 05/11/2011
You're addressing Here is the 64 grand question: Just how much fracking fluid returns via the wellbore?.
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Chris Salmon
Geologist and Computer Scientist
07:06 PM on 05/11/2011
This study did not find any frac fluid present in any of the wells tested.

http://www.nicholas.duke.edu/cgc/pnas2011.pdf
04:46 PM on 05/13/2011
Andthe answer:
"The hydrofracking mixture is then sucked out, put into trucks and shipped to wastewater treatment plants for cleaning. However, only about 10 to 40 percent of the water is recovered, and some critics say that contaminated water can find its way into groundwater supplies and wells."

Thus according to the State Attorney of Maryland's lawsuit fi

http://www.aboutlawsuits.com/maryland-hydrofracking-lawsuit-18119/

I suppose we'll see some finding now boys!
02:21 PM on 05/11/2011
some fun facts: The methane is just ONE issue...but the fracking fluid combined with improper wellbore treatment creats another

read the following regarding New Fracking Regulation­s in Wyoming as a direct result of water well contaminat­ion as concluded by the EPA in September 2010

http://sol­veclimaten­ews.com/ne­ws/2010090­2/epa-resu­lts-show-c­ontaminate­d-water-wy­oming-frac­king-zone

"The U.S. Environmen­tal Protection Agency (EPA) found methane from natural gas in seven of 19 wells that were tested in January of this year. Eleven had 2-butoexyt­hanol phosphate, a common solvent in fracking fluids that experts say can cause kidney failure, toxicity to the spleen, liver cancer and fertility problems."”
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Malcolm Hensley
Last of the Reagan Republicans
03:45 PM on 05/11/2011
This is the EPA's version:

http://www.epa.gov/region8/superfund/wy/pavillion/PavillionPressRelease31Aug2010.pdf

As for TBEP or 2 BE-P it's suppose to be a flame retardant used in flooring. I noticed it was not listed with your dangerous chemicals from Congressman's Waxman Fracking report.

http://www.epa.gov/region8/superfund/wy/pavillion/PavillionWyomingFactSheet.pdf this is an earlier report.
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Chris Salmon
Geologist and Computer Scientist
05:54 PM on 05/11/2011
From the paper: "In sum, the geochemical and isotopic
features for water we measured in the shallow wells from both
active and nonactive areas are consistent with historical data
and inconsistent with contamination from mixing Marcellus Shale
formation water or saline fracturing fluids"

http://www.nicholas.duke.edu/cgc/pnas2011.pdf
Sthernbull
I am one of the 53% that pays taxes.
12:59 PM on 05/11/2011
I am so happy we are able to get natural gas by fracking! I LOVE CHEAP energy Cheap Energy = JOBS! No wonder you democrats hate cheap energy.
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Malcolm Hensley
Last of the Reagan Republicans
01:33 PM on 05/11/2011
My world history teacher, Mr. Ramsey once said, "The world always had cheap labor, call them slaves call them serfs but the industrial revolution had to wait for cheap reliable energy!"

It changed how I perceived the world!

The Chinese figured this out and in 2009 burnt over 47% of all the coal consumed on the planet!
IWantTofu
Evolution. Now a political position.
12:01 PM on 05/13/2011
Then why are you mad a president Obama because we don't have cheap gasoline?

Regarding the fact that the Chinese burned over 47% of the coal consumed on the planet, did you know that half of our electricity is generated from coal? And that the Chinese coal is mined by chinese laborers that don't have anywhere near the same safey protections that our miners have in this country? Also, they are paid a lot less than our miners?
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12:57 PM on 05/11/2011
Has anyone else seen the propaganda on tv that gas windbags are trying to pass off as a reasoned arguement for how beautiful and green and plentful and affordable natural gas is?
12:26 PM on 05/11/2011
Of course oil and gas companies will dispute environmental reports. It's all about the Benjamins. It's OK to poison the water supply as long as they can get a mega-buck profit.
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rjohns3
Word are like bullets they don’t comeback.
12:02 PM on 05/11/2011
Fracking- injecting numerous toxic chemicals into the ground (where drinking water that humans consume also comes from) to break up the rock and release the gas so we can have the energy we need to leave lights on in rooms we are not in. Yea that is a smart & sound method.

Makes almost as much sense as report I read that postulated putting basically a giant curtain between the earth and the sun to cool the planet.... because photosynthesis is apparently over rated...
11:53 AM on 05/11/2011
Hmmmm. Duke or the gas industry? Duke of the gas industry? Hmmm. I'm going with coach K all the way.