11/02/2011 08:54 am ET | Updated Oct 11, 2012

Anne Hathaway In Valentino Couture: Look Of The Day

WHO: "One Day" actress Anne Hathaway
WHAT: It is common knowledge that Hathaway is a Valentino fanatic - she wore one of his creations while hosting the Oscars and was spotted en route to his runway show in Paris this summer - and she didn't let us down in this long-sleeved, couture number with beaded embellishments. Matching Christian Louboutin heels completed her gittery evening look.
WHERE: Joined by her "Princess Diaries" co-star Julie Andrews and Princess Charlene of Monaco, the actress was on-hand for the Princess Grace Awards Gala on November 1st in NYC.

Meanwhile, remember when Anne opted for big, voluminous hair?