10/03/2011 07:19 pm ET Updated Dec 03, 2011

Jennifer Aniston, Jill Biden Visit Breast Cancer Center In Virginia (PHOTOS)

It's not often you hear the names "Jill Biden" and "Jennifer Aniston" in the same sentence.

But the two women came together today in support of breast cancer research, visiting the the Breast Care Center at the Inova Alexandria Hospital at Mark Center in Virginia.

The two chic blondes were joined by Secretary of Health and Human Services Kathleen Sebelius and Kristin Hahn, co-producer of Aniston's newest film project, "Five." The Lifetime film series, composed of five short movies, chronicles different women's experiences with breast cancer.

The four women toured the center and met with doctors, who listened to the group talk about their own experiences with cancer.

Biden said that her "personal involvement with breast cancer started 20 years ago when several of my friends got breast cancer," compelling her to create a program in Delaware that invites doctors educate on the subject in classrooms.

Aniston, pool reports wrote, was particularly affected by nurse Ami Bhavsar, who spoke about the difficulties of helping patients without insurance.

The women's outfits did not distract from the experience, as Biden wore a very SLOTUS-esque ensemble consisting of a purple jersey dress, nude pumps and a long, silver necklace. Aniston kept it cool in jeans and a black sweater.

One unexpected accessory? A heart-shaped ring on the movie star's left hand, which had the press room buzzing after the event.

Take a look at Beiden, Aniston, Hahn and Sebelius on their Monday visit.

Jill Biden and Jen Aniston Visit Hospital