The South African native and her husband Prince Albert II stopped by the 123rd International Olympic Committee session in Durban, an annual meeting where IOC members choose the host city of the next Olympic games (candidates for the 2018 Winter Games are Munich, Annecy and PyeongChang, for those who were curious).
Princess Charlene wore a strapless black metallic top, black pants and a small black handbag, covering her famous shoulders with a elegant black shawl. More surprising than the black-on-black-on-black ensemble was her hair, which seemed to be in an uncharacteristically messy side-pony situation.
The couple is expected to honeymoon in nearby Umhlanga and host a dinner reception for 400 guests on Thursday night, the AFP reports.
Check out pictures of the newlyweds below.