WASHINGTON -- House Minority Leader Nancy Pelosi (D-Calif.) said Wednesday that the House Oversight and Government Reform Committee is playing politics with its vote to hold Attorney General Eric Holder in contempt of Congress, an action she said that even she didn't seek as House Speaker when she thought someone was legitimately deserving of it.

"I could have arrested Karl Rove on any given day," Pelosi said to laughter, during a sit-down with reporters. "I'm not kidding. There's a prison here in the Capitol ... If we had spotted him in the Capitol, we could have arrested him."

Rove was senior advisor and deputy chief of staff to former President George W. Bush from 2001 to 2007.

Asked on what grounds she could have arrested Rove, Pelosi replied, "Oh, any number. But there were some specific ones for his being in contempt of Congress. But we didn't."

The House committee is voting Wednesday whether to hold the U.S. attorney general in contempt of Congress for not handing over certain documents sought by the committee chairman, Rep. Darrell Issa (R-Calif.). The contempt vote comes after months of complaining by Issa that Holder is refusing to comply with subpoenas for materials relating to the Justice Department's botched Operation Fast and Furious. Holder, who has already given the committee 7,600 documents, maintains he can only provide so many materials without breaching confidentiality rules.

Pelosi sounded off on the ordeal ahead of the committee vote.

"This is just strictly political," she said. "It's just the irresponsibility of the Republicans. We want jobs. Why are they spending this time doing this?"

The Democratic leader also took a shot at Issa for abusing the process of holding an official in contempt.

"'Loose cannon' would sort of be like such a compliment to Darrell Issa. 'Loose cannon' would be a moderate phrase. This is an explosive device," she said. "It doesn't serve our country, and it undermines the true purpose of contempt of Congress."

"That's why I didn't arrest Karl Rove when I had the chance."

UPDATE: 4:38 p.m. -- The House Government Oversight and Reform Committee voted to hold Attorney General Eric Holder in contempt of Congress by a 23-17 vote. The full House will consider the matter sometime next week.

Below, photos from the contempt hearing and prior investigation:

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  • From left, House Minority Whip Steny Hoyer of Md., Rep. Maxine Waters, D-Calif., Rep. John Lewis, D-Ga., Rep, Charles Rangel, D-N.Y., and House Minority Leader Nancy Pelosi of Calif., right, and many House Democrats walk out of the Capitol during the vote to hold Attorney General Eric Holder in contempt, Thursday, June 28, 2012, on Capitol Hill in Washington. (AP Photo/J. Scott Applewhite)

  • House Oversight and Government Reform Committee Chairman Rep. Darrell Issa, R-Calif., left, and the committee's ranking Democrat Rep. Elijah Cummings, D-Md., go to the House Rules Committee, on Capitol Hill in Washington, Wednesday, June 27, 2012, to argue procedures as the House of Representatives prepares to vote on whether Attorney General Eric Holder is in contempt of Congress because he has refused to give the Oversight Committee all the documents it wants related to Operation Fast and Furious, the flawed gun-smuggling probe involving Mexican drug cartels. (AP Photo/J. Scott Applewhite)

  • Rep. Carolyn Maloney, D-N.Y., left, stretches out her hand to get the attention of Rep. Darrell Issa, R-Calif., chairman of the House Oversight and Government Reform Committee, as the panel considers a vote to hold Attorney General Eric Holder in contempt of Congress, on Capitol Hill in Washington, Wednesday, June 20, 2012. Rep. Elijah Cummings, D-Md., the ranking member, sits between them. (AP Photo/J. Scott Applewhite)

  • WASHINGTON, DC - JUNE 20: House Oversight and Government Reform Chairman Darrell Issa (R-CA) (C) talks with raking member U.S. Rep. Elijah Cummings (D-MD) (L) during a mark up hearing on Capitol Hill June 20, 2012 in Washington, DC. Issa and the committee Republicans called the hearing to vote on holding U.S. Attorney General Eric Holder in contempt of Congress for refusing to hand over documents the GOP says are key to their investigation into the failed Fast and Furious operation. Before the start of the hearing, the White House asserted the documents are protected by executive privilidge. (Photo by Chip Somodevilla/Getty Images)

  • Rep. Darrell Issa, R-Calif., center, chairman of the House Oversight and Government Reform Committee, confers with an aide as the panel considers a vote to hold Attorney General Eric Holder in contempt of Congress, on Capitol Hill in Washington, Wednesday, June 20, 2012. Rep. Elijah Cummings, D-Md., the ranking member, second from left, speaks with Rep. Carolyn Maloney, D-N.Y., who authored an amendment in support of Holder. In a showdown with President Barack Obama's administration, House Republicans had pressed for more Justice Department documents on the flawed gun-smuggling probe known as Operation Fast and Furious that resulted in hundreds of guns illicitly purchased in Arizona gun shops winding up in the hands of Mexican drug cartels. (AP Photo/J. Scott Applewhite)

  • Rep. Jason Chaffetz, R-Utah, center, debates Rep. Stephen Lynch, D-Mass., as the House Oversight and Government Reform Committee considers a vote to hold Attorney General Eric Holder in contempt of Congress, on Capitol Hill in Washington, Wednesday, June 20, 2012. (AP Photo/J. Scott Applewhite)

  • The House Oversight and Government Reform Committee, led by Chairman Darrell Issa, R-Calif., right, considers whether to hold Attorney General Eric Holder in contempt of Congress, on Capitol Hill in Washington, Wednesday, June 20, 2012. Rep. Elijah Cummings, D-Md., the ranking member, speaks at left. In a showdown with President Barack Obama's administration, House Republicans are pressing for more Justice Department documents on the flawed gun-smuggling probe known as Operation Fast and Furious that resulted in hundreds of guns illicitly purchased in Arizona gun shops winding up in the hands of Mexican drug cartels. (AP Photo/J. Scott Applewhite)

  • WASHINGTON, DC - JUNE 20: House Oversight and Government Reform raking member U.S. Rep. Elijah Cummings (D-MD) (R) hears from U.S. Rep. Dennis Kucinich (D-OH) during a mark up hearing with June 20, 2012 in Washington, DC. Chairman Darrell Issa (R-CA) and the committee Republicans called the hearing to vote on holding U.S. Attorney General Eric Holder in contempt of Congress for refusing to hand over documents the GOP says are key to their investigation into the failed Fast and Furious operation. Before the start of the hearing, the White House asserted the documents are protected by executive privilidge. (Photo by Chip Somodevilla/Getty Images)

  • Attorney General Eric holder speaks to reporters following his meeting on Capitol Hill in Washington, Tuesday, June 19, 2012. Holder wants a House panel to drop plans to try to hold him in contempt of Congress, and the panel's chairman wants more Justice Department documents regarding Operation Fast and Furious, a flawed gun-smuggling probe in Arizona. Holder and Rep. Issa met in an effort to resolve their dispute over the investigation of Fast and Furious by the House Oversight and Government Reform Committee that Issa chairs.(AP Photo/Susan Walsh)

  • Rep. Darrell Issa, R-Calif., speaks to reporters following his meeting with Attorney General Eric Holder on Capitol Hill in Washington, Tuesday, June 19, 2012. Holder wants a House panel to drop plans to try to hold him in contempt of Congress, and the panel's chairman wants more Justice Department documents regarding Operation Fast and Furious, a flawed gun-smuggling probe in Arizona. Holder and Issa met in an effort to resolve their dispute over the investigation of Fast and Furious by the House Oversight and Government Reform Committee that Issa chairs. (AP Photo/Susan Walsh)

  • Attorney General Eric Holder speaks to reporters following his meeting on Capitol Hill in Washington, Tuesday, June 19, 2012. Holder wants a House panel to drop plans to try to hold him in contempt of Congress, and the panel's chairman wants more Justice Department documents regarding Operation Fast and Furious, a flawed gun-smuggling probe in Arizona. Holder and Rep. Darrell Issa, a California Republican, met in an effort to resolve their dispute over the investigation of Fast and Furious by the House Oversight and Government Reform Committee that Issa chairs. (AP Photo/Susan Walsh)

  • Attorney General Eric Holder walks through Statuary Hall to speak to reporters following his meeting on Capitol Hill in Washington, Tuesday, June 19, 2012. (AP Photo/Susan Walsh)

  • FILE -In this Dec. 8, 2011 file photo, House Judiciary Committee member Rep. Darrell Issa, R-Calif., left, shakes hands with Attorney General Eric Holder on Capitol Hill in Washington. Holder is proposing to meet with Issa by Monday to settle a dispute over Justice Department documents the congressman is demanding on a flawed gun-smuggling probe. (AP Photo/Susan Walsh, File)

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