'Go On': Piper Perabo's Simone Flirts With Ryan

01/22/2013 08:33 am ET | Updated Jan 22, 2013

As soon as Ryan (Matthew Perry) joined "Go On's" therapy group, he began dominating meetings -- but the radio host wasn't the ensemble's first star player.

In Tuesday's episode of the NBC comedy, Ryan meets Simone (Piper Perabo of "Covert Affairs"), a popular former group member who competes with Ryan for the affections of their mutual friends. In HuffPost TV'sexclusive clip above, they have a drink as Ryan attempts to get ahead of Simone in their flirtatious competition.

Also in Tuesday's episode, football star Terrell Owens guest stars and brings together one of the least likely trios of all time: T.O., Mr. K (Brett Gelman) and Ryan's work buddy, Steven (John Cho). "Go On" also sees another sports star in Tuesday's episode: During his radio show, Ryan gets a call from Olympic track star Usain Bolt.

"Go On" airs Tuesdays at 8:30 p.m. EST on NBC.

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